In ancient times, obsidian, gold, silver, crystal, copper, bronze, after grinding and polishing to make mirrors; in 3000 BC, Egypt had ancient bronze mirrors for makeup; in the 1th century AD, there were large mirrors that could shine on the whole body; and portable mirrors in the Middle Ages that prevailed with combs in ivory or precious metal boxes
; from late 12th century to the beginning of 13th century, glass mirrors with silver or iron on the back appeared; Renaissance Venice was the center of the Mirror, and the mirrors produced were renowned for their high quality. In 16th century, the cylindrical method was invented to make plate glass, and the tin amalgam method with mercury attached to tin foil on glass was invented, and the metal mirror was gradually reduced. In the second half of 17th century, French invented flat glass with pouring method to produce high quality large glass mirrors. Mirrors and their borders increasingly become interior decorations. At the end of 18th century, large mirror were produced and used in furniture. Although the tin amalgam method is harmful to human body, it continues to be used until 19th century. In the 1835, J.von Leibiger, a German chemist, invented the chemical silver plating method to make the application of glass mirrors more popular.
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